Jules PATENÔTRE
- French Ambassador to the United States 1893-1897

Jules CAMBON
- French Ambassador to the United States 1897-1902

Jules JUSSERAND
- born February 18, 1855
- French Ambassador to the United States 1902-1924

Emile DAESCHNER
- born January 3, 1863
- Minister of Foreign Affairs 1905-1906 and 1912
- French Ambassador to the United States
1924-1925

Henri BERENGER
- born April 22, 1867
- French Ambassador to the United States
1925-26

Paul CLAUDEL
- born August 8, 1868
- French Ambassador to the United States
1926-1933

André LEFEBVRE de LA BOULAYE
- born January 22, 1876
- French Ambassador to the United States
1933-1937

Georges BONNET
- born July 22, 1889
- Delegate to the League of Nations in 1924, 1925, 1932, 1935
- Minister of Commerce in 1930 and 1938
- Minister of Finance 1933-34
- French Ambassador to the United States
1937-38

René DOYNEL de SAINT-QUENTIN
- born December 2, 1883
- French Ambassador to the United States
1938-40

Adrien TIXIER
- Delegate to the French National Committee in 1942

Henri HOPPENOT
- born October 25, 1891
- Delegate to the Provisionary Government of the French Republic in 1943

Henri BONNET
- born May 26, 1888
- Commissioner of Information to the FLN
Minister of Information of GRPF 1943-44
- French Ambassador to the United States
1944-1954

Maurice COUVE DE MURVILLE
- born January 24, 1907
- French Representative to NATO, October 1954
- French Ambassador to the United States
1954-56

Hervé ALPHAND
- born May 31, 1907
- French Representative to NATO
- French Ambassador to the United States
1956-1965

Charles LUCET
- born July 13, 1933
- French Ambassador to the United States
1965-72

Jacques KOSCIUSKO-MORIZET
- born March 7, 1921
- French Ambassador to the United States
1972-77

François LEFEBVRE de LABOULAYE
- born June 16, 1917
- French Ambassador to the United States
1977-81

Bernard VERNIER-PALLIEZ
- born March 2, 1918
- French Ambassador to the United States
1981-84

Emmanuel JACQUIN de MARGERIE
- born December 25, 1924
- French Ambassador to the United States,
1984-89

Jacques ANDREANI
- born November 22, 1929
- Head of the French Delegation to NATO
- Minister of Foreign Affairs
- French Ambassador to the United States
1989-95

François BUJON de L'ESTANG
- born August 21, 1940
- French Ambassador to the United States
1995-2002

Jean-David LEVITTE
- born June 14, 1946
- French Ambassador to the United States
2002-2007

Pierre VIMONT
- born June 15, 1949
- French Ambassador to the United States
2007-present